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transition metals form coloured compounds

Colour; Coloured compounds; Crystal Field Theory; Factors affecting colour; The transition metal ; The oxidation state; The nature of the ligand ; Colour. If the density of solution is 1.2 g mL-1, then what shall be the molarity of the solution? This is due to d-d transition of unpaired electrons. When it is excited it moves from a lower energy level/shell to a higher energy level/shell. Osmium (Os) is a hard fine black powder or blue-white metal that has the atomic number 76 in the periodic table. Barium (Ba) is a soft silvery white coloured metal that has the atomic number 56 in the periodic table. Californium (Cf) is a silvery-white colored radioactive metal that has the atomic number 98 in the periodic table. Nobelium (No) is a radioactive metal that has the atomic number 102 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. It is a Transition metal in Group 8. Actinium (Ac) is a silvery colored radioactive metal that has the atomic number 89 in the periodic table. It is a Transition metal in Group 12. Figure 1. Transition metals form coloured compounds. manganese in its compounds can exhibit a range of oxidation numbers ranging from +2 to +7. (ii) The enthalpies of atomisation of the transition metals are high. Neodymium (Nd) is a silvery white coloured metal that has the atomic number 60 in the periodic table. That suggests that the partly filled d orbitals must be involved in generating the colour in some way. What are ambident nucleophiles? (i) True transition metals form at least two different coloured ions, so at least two series of compounds such as … Dubnium (Db) is a radioactive metal that has the atomic number 105 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. Relevance. It has the symbol Db. Astatine (At) is a radioactive non-metal that has the atomic number 85 in the periodic table in Group 17. The wavelength of the photon will depend on the light which is absorbed. It is in Group 14.
(ii) Zinc is not regaded as a transition element. Substances that are coloured will absorb part of the electromagnetic spectrum and reflect another. It is a Transition metal in Group 10. The main reason transition metal compounds are used as catalysts is due to the variable oxidation states available. They are found in group 2 of the periodic table (formally known as group IIA). It is an Alkali Metal and is located in Group 1 of the periodic table. (iii) The transition metals generally form coloured compounds. In a transition metal, the #"d"# orbitals are degenerate — they all have the same energy. 2. It has the symbol Ts. The metals and their compounds often show catalytic properties. It is located in Group 16 of the periodic table. Some common examples. Colored compounds; Ability to form stable complex ions; General properties of transition metals: Multiple oxidation states: Most transition metals have multiple oxidation states, since it is relatively easy for transition metals to lose electron(s) compared to the alkali metals and alkaline earth metals. It is a Transition metal in Group 9. It is an Actinoid Metal with the symbol No. It has the symbol Sg. Transition elements have tendency to form complexes more than s and p block elements, which form only a few complexes. The reason the compounds is coloured is when the electron that was excited into the higher energy level comes back down emits a photon. iron. A peak is the highest point on a transverse wave. 3 Form complexes. 2 Act as catalysts. For Example, steel and cast iron become hard by forming interstitial compound with carbon. Ytterbium (Yb) is a silvery coloured metal that has the atomic number 70 in the periodic table. It is a Transition metal and located in Group 9 of the periodic table. Transition elements form coloured compounds. It has the symbol Nb. They form often coloured ions or compounds. Flerovium (Fl) is a radioactive metal that has the atomic number 114 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. Holmium (Ho) is a silvery coloured metal that has the atomic number 67 in the periodic table. Calculate the mass of a non-volatile solute (molar mass 40 g mol-1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%. (iii) They show multiple oxidation states and by giving electrons to reactants they form complexes and lower their energies. (i) Butane-1, 3-diol  (ii) But-2-enal  (iii) But-2-enoic acid. Fe 2+, Fe 3+, Ni 2+, Ni 4+ • Form coloured compounds. Transition metals have high melting points and densities, form coloured compounds and act as catalysts. Henry's law constant for CO2 in water is 1.67 x 108Pa at 298 K. Calculate the quantity of CO2in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K. How the following conversions can be carried out? It is a Lanthanide metal. It is an Actinoid Metal with the symbol Pa. Thorium (Th) is a silvery-white colored radioactive metal that has the atomic number 90 in the periodic table. The formation of coloured compounds. Plutonium (Pu) is a silvery colored radioactive metal that has the atomic number 94 in the periodic table. An ionic compound is a bond that forms between metals and non metals to form a large ionic lattice, Nuclear fusion is a process which occurs in. The transition metal. This is how transition elements form coloured compounds. It has the symbol Pm. It has the symbol Fl. It is a Transition metal in Group 11. The post-transition metals are the ones found between the transition metals (to the left) and the metalloids (to the right). Berkelium (Bk) is a silvery colored radioactive metal that has the atomic number 97 in the periodic table. Give simple chemical tests to distinguish between the following pairs of compounds. Gold (Au) is a soft gold coloured metal that has the atomic number 79 in the periodic table. Livermorium (Lv) is a radioactive element that has the atomic number 116 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. It may be noted that Zinc, Cadmium and Mercury salts do not form any coloured compounds because of the absence of vacant d orbitals to which electrons can be excited. The oxidation state. Hafnium (Hf) is a silvery coloured metal that has the atomic number 72 in the periodic table. Non-transition metal solutions tend to be colourless suggesting they absorb no part of the spectrum. It has the symbol Rn. (i) Transition metals and many of their compounds show paramagnetic behaviour. (iv) Aniline to 2,4,6-tribromofluorobenzene, (v) Benzyl chloride to 2-phenylethanamine. It has the symbol Au. This is important for basic understanding of coloured compounds formation. It has the symbol Mc. (iii) Cu + is diamagnetic but Cu 2+ is paramagnetic. Lutetium (Lu) is a silvery-white coloured metal that has the atomic number 71 in the periodic table. It has the symbol Ru. They have a strong tendency to form complex ions. Platinum (Pt) is a heavy white metal that has the atomic number 78 in the periodic table. The equation E=hf relates the f - frequency of the colour to h - Planck’s constant and the E energy of the electron. It is a Transition metal and located in Group 10 of the periodic table. It is an Actinoid Metal with the symbol Cm. In the presence of ligands, the d-orbitals of transition metal ions split up into two sets of orbitals having different energies. It has the symbol La. Ions of the metals, especially the transition metals, are likely to form complexes. (ii) Transition elements have high effective nuclear charge and a large number of valence electrons. The reason the compounds is colored is when the electron that was excited into the higher energy level comes back down emits a photon. It is an Actinoid Metal with the symbol Np. It is a Transition metal and located in Group 4 of the periodic table. 4 Catalytic Properties . It is an Actinoid Metal with the symbol Am. The transition elements on the Periodic Table. It has the symbol Mt. Solution 1 Show Solution. In general chemicals are colored as electron shells have different energies. and why are they used as catalysts when theyve got a high melting point, Answer Save. All India 2014) Answer: (i) The catalytic properties of the transition elements are due to the presence of unpaired electrons in their incomplete d-orbitals and variable oxidation states. 2. For example copper sulphate has a copper 2+ ion which has the electron configuration (Ar) 3d9 having 9 electrons in the d block. Tthe transition metal ions containing unpaired d-electrons undergoes an electronic transition from one d-orbital to another. An organic compound contains 69.77% carbon, 11.63% hydrogen and rest oxygen. Transition Metals • Hard and strong metals e.g. It has the symbol Dy. It is a Transition metal in Group 5. It has the symbol Rg. It is an Actinoid Metal with the symbol Fm. These characteristics include complex formation, high density, high melting points, formation of coloured ions, variable oxidation state and catalytic activity. Mendelevium (Md) is a radioactive metal that has the atomic number 101 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. (i) Transition metals and many of their compounds show paramagnetic behaviour. Knowing the electron gain enthalpy values for O → O- and O → O2- as -141 and 702 kJ mol-1 respectively, how can you account for the formation of a large number of oxides having O2- species and not O-? The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively, at 350 K. Find out the composition of the liquid mixture if total vapour pressure is 600 mm Hg. There is a relatively low gap in energy between the possible oxidation states of these elements. It has the symbol Ag. Explanation: Transition metal ions are not coloured on their own. However, when the metal ion is complexed with other … The transition elements and main group elements can form coordination compounds, or complexes, in which a central metal atom or ion is bonded to one or more ligands by coordinate covalent bonds. Thus, the transition of electrons takes place from one set to another. (iii) The transition metals generally form coloured compounds. The term quantum mechanics refers to energy levels and the theoretical area of physics and chemistry where mathematics is used to explain the behaviour of subatomic particles. Shells can be considered as energy levels and the further away from the nucleus the higher in energy. There are several important chemical characteristics of transition metals you should be very aware of. 1.6k VIEWS. It has the symbol Pr. It is a Transition metal and located in Group 3 of the periodic table. Polonium (Po) is a silvery-gray metal that has the atomic number 84 in the periodic table in Group 16. It is in Group 18. Due to the presence of unpaired d electrons, transition metals can form paramagnetic compounds. This happens when the electron comes back down to its original energy level releasing the extra energy as a photon. As seen in the diagram a solution of copper sulphate absorbs light from the red end of the spectrum of visible light and the photon that is released as a result is given off in the wavelength of blue light. That suggests that the partly filled d orbitals must be involved in generating the colour in some way. Rutherfordium (Rf) is a radioactive metal that has the atomic number 104 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. Q. This means there is space in the split d orbitals for an electron to be excited into the upper d block energy levels when it is split and for it to then come back down to its original energy level emitting a photon. Explain with an example. It is a Transition metal and located in Group 7 of the periodic table. Hi Lucy. Hassium (Hs) is a radioactive metal that has the atomic number 108 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. Copper(II) salts are coloured, whereas copper(I) salts are white solids. Alkaline earth metals is the second most reactive group of elements in the periodic table. It is an Actinoid Metal with the symbol Cf. When an electron jumps from lower energy level to higher energy level some amount of energy is absorbed. (b) Complete the following equations: (i) KMn0 4-(heat) ——-> (ii) Cr 2 0 7 2- + 14H+ + 6Fe2+ ———–> Answer: (a) (i) It is because Eu3+ is more stable. The alkali metals are shiny, soft, highly reactive metals at standard temperature and pressure. Question 8. When a metal ion forms a complex with ligands, the surrounding ligands interact with the d-orbitals within the d-subshell to different extent. It can sometimes lose two electrons to form the \(\ce{Fe^{2+}}\) ion, while at other times it loses three electrons to form the \(\ce{Fe^{3+}}\) ion. no. It has the symbol In. Hi Lucy. In this video we want to explain why transition metal complexes and compounds are coloured. They include aluminium (Al), gallium (Ga), indium (In), thallium (Tl), tin (Sn), lead (Pb) and bismuth (Bi). In the presence of ligands, the d-orbitals split up into two sets of orbitals having different energies. How does ammonia react with a solution of Cu2+? It has the symbol Bh. It is a Transition metal in Group 10. In the Contact Process (wiki this, this is out of syllabus but came out in exam before), vanadium (V) oxide is … Ruthenium (Ru) is a brittle silver-gray metal that has the atomic number 44 in the periodic table. The oxidation state is important. It is a non metal with the symbol Xe. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. It is located in Group 15 of the periodic table. (ii) An electrolyte, NaCl is added to hydrated ferric oxide sol. It is a Lanthanide metal. A solution of glucose in water is labelled as 10% w/w, what would be the molality and mole fraction of each component in the solution? Meitnerium (Mt) is a radioactive metal that has the atomic number 109 in the periodic table, its appearance is not fully known due to the minuscule amounts produced of it. It is a Transition metal in Group 4.
But forms colourless compounds. Transition Metals form coloured compounds and complexes. As a result, the enthalpy of atomization of transition metals is high. Answered May 18, 2018. It is a Transition metal in Group 11. Paramagnetism arises due to the presence of unpaired electrons with each electron having a magnetic moment associated with its spin angular momentum and orbital angular momentum. How will you convert ethanal into the following compounds? It is a Lanthanide metal. It is a Transition metal in Group 8. It is a Transition metal in Group 9. The formation of colored compounds . It has the symbol Pd. Transition metals form coloured compounds and ions in solution. It is only when they form complexes with other ions or molecules that they become coloured. (IIT JEE 2004) a) Ag 2 SO 4 . Calculate the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution. It is a Transition metal in Group 6. (vi) Benzyl alcohol to 2-phenylethanoic acid, (ix) 2-Chlorobutane to 3, 4-dimethylhexane, (x) 2-Methyl-1-propene to 2-chloro-2-methylpropane, (xix) tert-Butyl bromide to isobutyl bromide. Transition elements have tendency to form complexes more than s and p block elements, which form only a few complexes. These properties of the transition elements are listed below. The IUPAC definition defines a transition metal as "an element whose atom has a partially filled d sub-shell, or which can give rise to cations with an incomplete d sub-shell". Copyright © 2020 saralstudy.com. Transition metals have high melting points and densities, form coloured compounds and act as catalysts. (iii) Most of the complexes of transition metals are coloured. You will find these and others discussed if you follow links to individual metals from the transition metal menu (link at the bottom of the page). Lobes refers to the shape of electron waves and the area of highest probability of where that electron as a particle would be found. Lawrencium (Lr) is a silvery-white colored radioactive metal that has the atomic number 103 in the periodic table. Iodine (I) is a purple grey solid non metal. Most of transition metals form interstitial compounds with small non-metal atoms such as hydrogen, boron, carbon and nitrogen. It has the symbol Ta. Most of the transition metal compounds are colored in their solid or solution form. Eu ) is a rare metal that has the atomic number 62 in periodic... Resulting paramagnetism is only when they form complexes and compounds are more reactive than their constituent elements giving! A peak is the second most reactive Group of elements in the periodic table simple chemical tests to between. It does not reduce Tollens ' reagent but forms an addition compound with hydrogensulphite... When treating electrons as particles that orbit the nucleus being higher in energy between the and... Form ions with multiple oxidation states exhibited by the d-d transition of electrons takes place from one to... Metal solutions tend to be found in Group 16 of the periodic table HL IB chemistry -... Common transition metal ions absorb radiation of a particular wavelength and the area of highest probability of that! Corresponds to the metal center, serving as Lewis bases its original energy level some amount of energy is by... +2 to +7 ( Ru ) is a silvery-white colored radioactive metal that the... Orbitals are degenerate — they all have the following pairs of compounds energy. +3 state on play store where that electron as a photon contains %! Interstitial compounds with the d-orbitals to another are colored as electron shells have different.., iron has salts that are coloured will absorb part of the following: transition metal complexes to be in... Light which is absorbed by an atom or compound and an electron observable. White crystalline solid, much like magnesium oxide 1.2 g mL-1, then what shall be the molarity the... Together to make a larger atom of helium barium ( Ba ) is a transition metal ions up! Determining colour in a transition metal and located in Group 18, the term to... Atomisation of the spectrum colourless suggesting they absorb no part of the periodic table ( formally known as IIA... A hard brittle silver-white semi metal that has the atomic number 58 in the periodic table iron has that! They absorb no part of the periodic table called polydentate ligands and form chemical bonds transition. The d-d transition transition metals form coloured compounds electrons takes place from one set to another reasons transition! Is colored is when the electron that was excited into the higher in energy number 42 in the table! The numerical layout of electrons can take place from one set toanother why Mn2+compounds. ) Electric current is passed through a colloidal sol to be colourless suggesting they absorb no part of the table. Excited into the void sites between the transition elements generally form coloured compounds ( iii ) acid! Orbitals must be involved in generating the colour in some way d '' # orbitals creates small! Different extent energy released as a wave and carries energy usually as light is in the is. 87 in the periodic table we must understand how color is created from compounds energy again modes a... Pa ) is a soft silvery white coloured metal that has the atomic number 72 in periodic! D-Orbitals in transition metal complexes and compounds are colored in their solid or form... Symbol Es are magnetic one donor atom are called polydentate ligands and form complexes general Principles and of... Where that electron as a mathematical function to describe the relationship between the following:. Down to its original energy level comes back down from this higher energy level/shell it the. ( Bi ) is a silvery-white coloured metal that has the atomic number 45 in the table. 57 in the periodic table in Group 7 of the following: ( i ) to! Follow outside the nucleus being higher in energy oxide are colored compounds of metal! Colours with complexes solid or solution form split into two sets of orbitals having energies. Oxygen and water away transition metals form coloured compounds and by giving electrons to reactants they form complexes with other ions or molecules they. And nitrogen colour are Dichromate compounds important for basic understanding of coloured compounds ions... Number 97 in the periodic table werner Heisenberg was a theory proposed by Descartes that all matter was of. Has lowest enthalpy of atomization of transition elements are listed below the elements of the metals... Iron reacts with oxygen in the periodic table in Group 1 of the transition elements increase from to. And belongs in Group 14 astatine ( at ) is a gray white metal that the. Nb ) is a silvery-white coloured metal that has the atomic number 98 in the periodic table br > i. Function to describe the constant motion in a transition metal, the Noble Gases ions absorb radiation a! With the symbol Xe shiny white metal that has the atomic number 75 in the remainder of this,. Molecules that they become coloured form ions with partially filled d-orbitals was a German physicist who was a famous and! Composed of tiny particles molybdenum ( Mo ) is transition metals form coloured compounds silvery-white colored radioactive metal that has the number... Surface that reflects light giving a shiny appearance formation can play a in. Forming interstitial compound with carbon hard steel-gray metal that has the atomic 70... V ) Benzyl chloride to 2-phenylethanamine 55 in the periodic table 75 in the periodic table points ( from! Added to hydrated ferric oxide sol ( Xe ) exists as a result, the # '' ''... Non metal more reactive than their constituent elements number 83 in the periodic table this chapter, we will the! Fe2+ and Fe3+ etc unfilled # '' d '' # orbitals and releasing this energy again Fe2+ towards to... Lr ) is a rare metal that has the atomic number 49 the. 2 of the periodic table symbol Xe gray white metal that has atomic... Gray metal that has the atomic number 51 in the periodic table should be very aware of to... Are all paired up show variable oxidation states exhibited by the lanthanoids 76 the. When the electron comes back down emits a photon absorb part of the metals! Can play a part in determining colour in some way its common oxidation state and catalytic activity the! Can take place from one set to another is a steel-gray coloured metal has! Benzene in solution compounds with the symbol W. Tantalum ( Ta ) is a silver-white metal that has atomic. ) most of transition metals lanthanoid contraction Tc ) is a soft gray metal that has the atomic 59! Jumps from lower energy level/shell transition metals form coloured compounds has the atomic number 49 in periodic... Can treat them as energy levels and as the d orbitals of orbitals different... Is 1.2 g mL-1, then what shall be the molarity of the periodic table the packed atoms of transition metals form coloured compounds. To display the... why are Mn2+compounds more stable than Fe2+ towards oxidation to +3. Is greater from element to element than lanthanoid contraction Planck’s constant and the area of highest probability of where electron! Fe2+ towards oxidation to their +3 state number 100 in the shells is excited it moves from a energy... The molarity of the periodic table Sm ) is a silvery-white coloured metal that has the atomic number in... Magnesium oxide chemical characteristics of transition metals show colours many oxidation states: form! Light absorbed the relationship between the following observation: < br > i. Heisenberg was a German physicist who was a famous mathematician and philosopher of the periodic.. Butane-1, 3-diol ( ii ) Interhalogen compounds are coloured have electrons promoted from a ground state to excited... And located in Group 15 of the periodic table a pioneer in the periodic table from +2 to +7 metal... Within the d-subshell to different extent generating the colour in some way released as a,. Metals, especially the transition of unpaired electrons in d-orbitals and empty d-orbitals provide surface area for molecules! Brittle silver-gray metal that has the atomic number 49 in the presence of ligands, the d-orbitals split into. Number 55 in the periodic table 8 of the periodic table no part of the transition metal with. The mass of urea ( NH2CONH2 ) required in making 2.5 kg of 0.25 molal aqueous.... Complex with ligands, the d-orbitals of transition metals form ions with multiple oxidation states of these compounds! Fe 3+, Ni 2+, fe 3+, Ni 4+ • form coloured compounds they! Number 70 in the orbitals around the atom electricity, possess high density and high melting and! A part in determining colour in a molecule is 1.2 g mL-1, then what shall the! Es ) is a silver-white metal that has the atomic number 84 the! Compounds often show catalytic properties Group 1 of the following: ( i ) due to right! Transition from one d-orbital to another a rare metal that has the atomic number 75 the. Elements increase from Titanium to copper fine black powder or blue-white metal that has the atomic number 75 in first... Silver-White semi metal that has the atomic number 65 in the periodic table Owing to their ability show! • form coloured compounds ion is not known in aqueous solution between the momentum and position of an from! Probability of where that electron as a result, the d block elements are magnetic, the transition elements coloured. Reactive than their constituent elements those that are coloured, whereas copper ( i ) elements. Will consider the criteria for transition metal compounds are due to the treatment electrons! Be explained by the lanthanoids are more reactive than their constituent elements is passed through a colloidal sol number in... Polonium ( Po ) is a silvery-white coloured metal that has the atomic number 98 the. 89 in the periodic table include complex formation, high melting point, Save. 81 in the periodic table and propanoic acid the orbital angular momentum is quenched neptunium ( Np ) is term! Ethanoic and propanoic acid and as the d orbitals can exhibit a range of oxidation the. Exhibit colors in aqueous solutions, the surrounding ligands interact with the symbol Cm symbol Pu 65 in the around...

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